Order of operations is pretty straightforward. The acronym PEMDAS stands for Parentheses, Exponents, Multiplication, Division, Addition, Subtraction. (As Pandq already mentioned) This is simply the order in which you solve things when faced with simplifying a problem. Figure out anything inside parentheses first, then solve anything that has an exponent on it next.
Multiplication and division come after exponents and parentheses. Multiplication and division are actually the same thing in reverse, (1/3 is the same as 1*0.3333...) so you can multiply and divide things in whatever order you want and it won't change the answer.
Addition and subtraction are also the same thing, just reverses of each other. (1+3 is the same as 1- negative 3) You can do addition and subtraction in whatever order you want and get the
same answer.
EDIT SO SOWWIE FO DOOUBLE
Example:
Simplify this problem: x=(2(4+5)-8^2+6)/4
x=(2(9)-8^2+6)/4 (Solve the parentheses that you can first. The larger parentheses cannot be solved yet, as we need to do more algebra first.)
x=(2(9)-64+6)/4 (Solve the exponent, which is indicated by a ^ on a computer. 8 squared is 64. Note that it is not negative 8 squared, it is just 8 squared. The minus in front of the eight only makes it a negative if it has no exponents.)
x=(18-64+6)/4 (Do whatever multiplication or division you can.)
x=(-40)/4 (Now that you have finished simplifying the parentheses, you can divide by 4.)
x=-10